To unsocket and remove socketed gems, jewels, or runes from items and gears in Diablo 2 Resurrected, you need to unlock Horadric Cube in Halls of the Dead dungeon in the Dry Hills during Act 2 to use a Hel rune, a Scroll of Town Portal, and the socketed item, and then click on the Transmute button.

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Diablo 3 remove gems from sockets